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| subject: | Pnu 722 |
-> Buckyballs were well after I got my Chem degree in '67, and
That's three years more recent than when I got mine.
-> I've been in IT since. But from what I understand, modelling
-> this as a "super benzene ring", it wouldn't be
"charged"--it's
-> an organic molecule. There are molecular orbitals similar to
-> atomic orbitals, though their energy levels aren't nearly as
-> precise--which is why dyes radiate/absorb over wide bands.
-> I'd say the electrons can do the QM jump between orbitals and
-> radiate, but I'm not sure I'd consider that a moving charge.
If buckyballs behave like huge "aromatic" molecules, then there are
large numbers of electrons (one per carbon atom, I think) that can roam
fairly freely over the surface of the ball, occupying an equal number
of almost-degenerate orbitals that are formed from the overlapping "p"
orbitals of the atoms. These delocalized electrons could vibrate around
the ball, forming standing-waves of charge on the surface. As these
waves change, radiation would be absorbed or emitted.
I think....
dow
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